您可以考虑使用XML Spreadsheet 2003格式创建文件。这是一种简单的XML格式，使用了一个文档化的模式。

只想添加另一个引用到直接解决您问题的第三方解决方案：http://www.officewriter.com

（免责声明：我为制作OfficeWriter的公司SoftArtisans工作）

您可以使用此库创建格式良好的Excel文件：http://officehelper.codeplex.com/documentation参见以下示例：

using (ExcelHelper helper = new ExcelHelper(TEMPLATE_FILE_NAME, GENERATED_FILE_NAME))
{
    helper.Direction = ExcelHelper.DirectionType.TOP_TO_DOWN;
    helper.CurrentSheetName = "Sheet1";
    helper.CurrentPosition = new CellRef("C3");

    //the template xlsx should contains the named range "header"; use the command "insert"/"name".
    helper.InsertRange("header");

    //the template xlsx should contains the named range "sample1";
    //inside this range you should have cells with these values:
    //<name> , <value> and <comment>, which will be replaced by the values from the getSample()
    CellRangeTemplate sample1 = helper.CreateCellRangeTemplate("sample1", new List<string> {"name", "value", "comment"}); 
    helper.InsertRange(sample1, getSample());

    //you could use here other named ranges to insert new cells and call InsertRange as many times you want, 
    //it will be copied one after another;
    //even you can change direction or the current cell/sheet before you insert

    //typically you put all your "template ranges" (the names) on the same sheet and then you just delete it
    helper.DeleteSheet("Sheet3");
}        

示例如下：

private IEnumerable<List<object>> getSample()
{
    var random = new Random();

    for (int loop = 0; loop < 3000; loop++)
    {
        yield return new List<object> {"test", DateTime.Now.AddDays(random.NextDouble()*100 - 50), loop};
    }
}

你试过sylk吗？

我们曾经在经典的asp中生成excelsheets作为sylk，现在我们也在寻找excelsheeter。

sylk的优点是，可以格式化单元格。

我成功地使用了以下开源项目：

用于OOXML格式的ExcelPackage（Office 2007）XLS格式的NPOI（Office 2003）。NPOI 2.0（Beta版）也支持XLSX。

看看我的博客帖子：

在C中创建Excel电子表格.XLS和.XLSX#

带有Excel表格和动态图表的NPOI

public class GridViewExportUtil
{
    public static void Export(string fileName, GridView gv)
    {
        HttpContext.Current.Response.Clear();
        HttpContext.Current.Response.AddHeader(
            "content-disposition", string.Format("attachment; filename={0}", fileName));
        HttpContext.Current.Response.ContentType = "application/ms-excel";

        using (StringWriter sw = new StringWriter())
        {
            using (HtmlTextWriter htw = new HtmlTextWriter(sw))
            {
                //  Create a form to contain the grid
                Table table = new Table();

                //  add the header row to the table
                if (gv.HeaderRow != null)
                {
                    GridViewExportUtil.PrepareControlForExport(gv.HeaderRow);
                    table.Rows.Add(gv.HeaderRow);
                }

                //  add each of the data rows to the table
                foreach (GridViewRow row in gv.Rows)
                {
                    GridViewExportUtil.PrepareControlForExport(row);
                    table.Rows.Add(row);
                }

                //  add the footer row to the table
                if (gv.FooterRow != null)
                {
                    GridViewExportUtil.PrepareControlForExport(gv.FooterRow);
                    table.Rows.Add(gv.FooterRow);
                }

                //  render the table into the htmlwriter
                table.RenderControl(htw);

                //  render the htmlwriter into the response
                HttpContext.Current.Response.Write(sw.ToString());
                HttpContext.Current.Response.End();
            }
        }
    }

    /// <summary>
    /// Replace any of the contained controls with literals
    /// </summary>
    /// <param name="control"></param>
    private static void PrepareControlForExport(Control control)
    {
        for (int i = 0; i < control.Controls.Count; i++)
        {
            Control current = control.Controls[i];
            if (current is LinkButton)
            {
                control.Controls.Remove(current);
                control.Controls.AddAt(i, new LiteralControl((current as LinkButton).Text));
            }
            else if (current is ImageButton)
            {
                control.Controls.Remove(current);
                control.Controls.AddAt(i, new LiteralControl((current as ImageButton).AlternateText));
            }
            else if (current is HyperLink)
            {
                control.Controls.Remove(current);
                control.Controls.AddAt(i, new LiteralControl((current as HyperLink).Text));
            }
            else if (current is DropDownList)
            {
                control.Controls.Remove(current);
                control.Controls.AddAt(i, new LiteralControl((current as DropDownList).SelectedItem.Text));
            }
            else if (current is CheckBox)
            {
                control.Controls.Remove(current);
                control.Controls.AddAt(i, new LiteralControl((current as CheckBox).Checked ? "True" : "False"));
            }

            if (current.HasControls())
            {
                GridViewExportUtil.PrepareControlForExport(current);
            }
        }
    }
}

嗨，这个解决方案是将网格视图导出到excel文件中，这可能会帮助您