你可以创建自己的字典包装器，就像这样，作为奖励，它支持空值作为键:

/// <summary>
/// Dictionary which supports duplicates and null entries
/// </summary>
/// <typeparam name="TKey">Type of key</typeparam>
/// <typeparam name="TValue">Type of items</typeparam>
public class OpenDictionary<TKey, TValue>
{
    private readonly Lazy<List<TValue>> _nullStorage = new Lazy<List<TValue>>(
        () => new List<TValue>());

    private readonly Dictionary<TKey, List<TValue>> _innerDictionary =
        new Dictionary<TKey, List<TValue>>();

    /// <summary>
    /// Get all entries
    /// </summary>
    public IEnumerable<TValue> Values =>
        _innerDictionary.Values
            .SelectMany(x => x)
            .Concat(_nullStorage.Value);

    /// <summary>
    /// Add an item
    /// </summary>
    public OpenDictionary<TKey, TValue> Add(TKey key, TValue item)
    {
        if (ReferenceEquals(key, null))
            _nullStorage.Value.Add(item);
        else
        {
            if (!_innerDictionary.ContainsKey(key))
                _innerDictionary.Add(key, new List<TValue>());

            _innerDictionary[key].Add(item);
        }

        return this;
    }

    /// <summary>
    /// Remove an entry by key
    /// </summary>
    public OpenDictionary<TKey, TValue> RemoveEntryByKey(TKey key, TValue entry)
    {
        if (ReferenceEquals(key, null))
        {
            int targetIdx = _nullStorage.Value.FindIndex(x => x.Equals(entry));
            if (targetIdx < 0)
                return this;

            _nullStorage.Value.RemoveAt(targetIdx);
        }
        else
        {
            if (!_innerDictionary.ContainsKey(key))
                return this;

            List<TValue> targetChain = _innerDictionary[key];
            if (targetChain.Count == 0)
                return this;

            int targetIdx = targetChain.FindIndex(x => x.Equals(entry));
            if (targetIdx < 0)
                return this;

            targetChain.RemoveAt(targetIdx);
        }

        return this;
    }

    /// <summary>
    /// Remove all entries by key
    /// </summary>
    public OpenDictionary<TKey, TValue> RemoveAllEntriesByKey(TKey key)
    {
        if (ReferenceEquals(key, null))
        {
            if (_nullStorage.IsValueCreated)
                _nullStorage.Value.Clear();
        }       
        else
        {
            if (_innerDictionary.ContainsKey(key))
                _innerDictionary[key].Clear();
        }

        return this;
    }

    /// <summary>
    /// Try get entries by key
    /// </summary>
    public bool TryGetEntries(TKey key, out IReadOnlyList<TValue> entries)
    {
        entries = null;

        if (ReferenceEquals(key, null))
        {
            if (_nullStorage.IsValueCreated)
            {
                entries = _nullStorage.Value;
                return true;
            }
            else return false;
        }
        else
        {
            if (_innerDictionary.ContainsKey(key))
            {
                entries = _innerDictionary[key];
                return true;
            }
            else return false;
        }
    }
}

用法示例:

var dictionary = new OpenDictionary<string, int>();
dictionary.Add("1", 1); 
// The next line won't throw an exception; 
dictionary.Add("1", 2);

dictionary.TryGetEntries("1", out List<int> result); 
// result is { 1, 2 }

dictionary.Add(null, 42);
dictionary.Add(null, 24);
dictionary.TryGetEntries(null, out List<int> result); 
// result is { 42, 24 }

List类实际上适用于包含重复项的键/值集合，在此集合上进行迭代。例子:

List<KeyValuePair<string, string>> list = new List<KeyValuePair<string, string>>();

// add some values to the collection here

for (int i = 0;  i < list.Count;  i++)
{
    Print(list[i].Key, list[i].Value);
}

如果你正在使用>= .NET 4，那么你可以使用元组类:

// declaration
var list = new List<Tuple<string, List<object>>>();

// to add an item to the list
var item = Tuple<string, List<object>>("key", new List<object>);
list.Add(item);

// to iterate
foreach(var i in list)
{
    Console.WriteLine(i.Item1.ToString());
}

关于使用Lookup的非常重要的注意事项:

你可以通过调用一个实现IEnumerable(T)的对象上的Lookup(TKey, TElement)实例来创建一个Lookup(TKey, TElement)实例。

没有公共构造函数来创建Lookup(TKey、TElement)的新实例。此外，Lookup(TKey, TElement)对象是不可变的，也就是说，在创建Lookup(TKey, TElement)对象后，您不能从它添加或删除元素或键。

(从MSDN)

我认为这对大多数人来说都是一种阻碍。

当使用List<KeyValuePair<string, object>>选项时，你可以使用LINQ来进行搜索:

List<KeyValuePair<string, object>> myList = new List<KeyValuePair<string, object>>();
//fill it here
var q = from a in myList Where a.Key.Equals("somevalue") Select a.Value
if(q.Count() > 0){ //you've got your value }

你可以定义一个方法来构建复合字符串键 在任何你想要使用字典的地方，你都必须使用这个方法来构建你的键 例如:

private string keyBuilder(int key1, int key2)
{
    return string.Format("{0}/{1}", key1, key2);
}

使用:

myDict.ContainsKey(keyBuilder(key1, key2))