这个看起来好一点:

var rgb = $('#selector').css('backgroundColor').match(/\d+/g);
var r   = parseInt(rgb[0], 10);
var g   = parseInt(rgb[1], 10);
var b   = parseInt(rgb[2], 10);
var hex = '#'+ r.toString(16) + g.toString(16) + b.toString(16);

更简洁的一句话:

var rgb = $('#selector').css('backgroundColor').match(/\d+/g);
var hex = '#'+ Number(rgb[0]).toString(16) + Number(rgb[1]).toString(16) + Number(rgb[2]).toString(16);

强制jQuery总是返回十六进制:

$.cssHooks.backgroundColor = {
    get: function(elem) {
        if (elem.currentStyle)
            var bg = elem.currentStyle["backgroundColor"];
        else if (window.getComputedStyle) {
            var bg = document.defaultView.getComputedStyle(elem,
                null).getPropertyValue("background-color");
        }
        if (bg.search("rgb") == -1) {
            return bg;
        } else {
            bg = bg.match(/\d+/g);
            function hex(x) {
                return ("0" + parseInt(x).toString(16)).slice(-2);
            }
            return "#" + hex(bg[0]) + hex(bg[1]) + hex(bg[2]);
        }
    }
}

改进功能“hex”

function hex(x){
    return isNaN(x) ? "00" : hexDigits[x >> 4] + hexDigits[x & 0xf];
    // or option without hexDigits array
    return (x >> 4).toString(16)+(x & 0xf).toString(16);
}

由于问题是使用JQuery，下面是一个基于Daniel Elliott代码的JQuery插件:

$.fn.cssAsHex = function(colorProp) {

    var hexDigits = '0123456789abcdef';

    function hex(x) {
        return isNaN(x) ? '00' : hexDigits[(x - x % 16) / 16] + hexDigits[x % 16];
    };

    // Convert RGB color to Hex format
    function rgb2hex(rgb) {
        var rgbRegex = rgb.match(/^rgb\((\d+),\s*(\d+),\s*(\d+)\)$/);
        return '#' + hex(rgbRegex[1]) + hex(rgbRegex[2]) + hex(rgbRegex[3]);
    };

    return rgb2hex(this.css(colorProp));
};

像这样使用它:

var hexBackgroundColor = $('#myElement').cssAsHex('background-color');

var hexDigits = new Array
        ("0","1","2","3","4","5","6","7","8","9","a","b","c","d","e","f"); 

//Function to convert rgb color to hex format
function rgb2hex(rgb) {
 rgb = rgb.match(/^rgb\((\d+),\s*(\d+),\s*(\d+)\)$/);
 return "#" + hex(rgb[1]) + hex(rgb[2]) + hex(rgb[3]);
}

function hex(x) {
  return isNaN(x) ? "00" : hexDigits[(x - x % 16) / 16] + hexDigits[x % 16];
 }

(源)

下面是一个ES6 one liner，它不使用jQuery:

var rgb = document.querySelector('#selector').style['background-color'];
return '#' + rgb.substr(4, rgb.indexOf(')') - 4).split(',').map((color) => parseInt(color).toString(16).padStart(2, '0')).join('');

对于所有函数式编程爱好者，这里有一个有点函数式的方法:)

const getHexColor = (rgbValue) =>
  rgbValue.replace("rgb(", "").replace(")", "").split(",")
    .map(colorValue => (colorValue > 15 ? "0" : "") + colorValue.toString(16))
    .reduce((acc, hexValue) => acc + hexValue, "#")

然后这样使用它:

const testRGB = "rgb(13,23,12)"
getHexColor(testRGB)