支持最短路径和.net核心：

    public static string BytesToString(byte[] ba) =>
        ba.Aggregate(new StringBuilder(32), (sb, b) => sb.Append(b.ToString("X2"))).ToString();

未针对速度进行优化，但比大多数答案（.NET 4.0）更LINQy：

<Extension()>
Public Function FromHexToByteArray(hex As String) As Byte()
    hex = If(hex, String.Empty)
    If hex.Length Mod 2 = 1 Then hex = "0" & hex
    Return Enumerable.Range(0, hex.Length \ 2).Select(Function(i) Convert.ToByte(hex.Substring(i * 2, 2), 16)).ToArray
End Function

<Extension()>
Public Function ToHexString(bytes As IEnumerable(Of Byte)) As String
    Return String.Concat(bytes.Select(Function(b) b.ToString("X2")))
End Function

这里不想赘述很多答案，但我发现了一个十六进制字符串解析器的相当优化（比公认的好4.5倍）、简单的实现。首先，我的测试输出（第一批是我的实现）：

Give me that string:
04c63f7842740c77e545bb0b2ade90b384f119f6ab57b680b7aa575a2f40939f

Time to parse 100,000 times: 50.4192 ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

Accepted answer: (StringToByteArray)
Time to parse 100000 times: 233.1264ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With Mono's implementation:
Time to parse 100000 times: 777.2544ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With SoapHexBinary:
Time to parse 100000 times: 845.1456ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

base64和“BitConverter'd”行用于测试正确性。请注意，它们是相等的。

实施：

public static byte[] ToByteArrayFromHex(string hexString)
{
  if (hexString.Length % 2 != 0) throw new ArgumentException("String must have an even length");
  var array = new byte[hexString.Length / 2];
  for (int i = 0; i < hexString.Length; i += 2)
  {
    array[i/2] = ByteFromTwoChars(hexString[i], hexString[i + 1]);
  }
  return array;
}

private static byte ByteFromTwoChars(char p, char p_2)
{
  byte ret;
  if (p <= '9' && p >= '0')
  {
    ret = (byte) ((p - '0') << 4);
  }
  else if (p <= 'f' && p >= 'a')
  {
    ret = (byte) ((p - 'a' + 10) << 4);
  }
  else if (p <= 'F' && p >= 'A')
  {
    ret = (byte) ((p - 'A' + 10) << 4);
  } else throw new ArgumentException("Char is not a hex digit: " + p,"p");

  if (p_2 <= '9' && p_2 >= '0')
  {
    ret |= (byte) ((p_2 - '0'));
  }
  else if (p_2 <= 'f' && p_2 >= 'a')
  {
    ret |= (byte) ((p_2 - 'a' + 10));
  }
  else if (p_2 <= 'F' && p_2 >= 'A')
  {
    ret |= (byte) ((p_2 - 'A' + 10));
  } else throw new ArgumentException("Char is not a hex digit: " + p_2, "p_2");

  return ret;
}

我尝试了一些不安全的东西，并将（显然是冗余的）字符移动到另一个方法来蚕食if序列，但这是最快的。

（我承认这回答了一半的问题。我觉得字符串->字节[]转换不足，而字节[]->字符串角度似乎被很好地覆盖了。因此，这个答案。）

Waleed Eissa代码的逆函数（十六进制字符串到字节数组）：

    public static byte[] HexToBytes(this string hexString)        
    {
        byte[] b = new byte[hexString.Length / 2];            
        char c;
        for (int i = 0; i < hexString.Length / 2; i++)
        {
            c = hexString[i * 2];
            b[i] = (byte)((c < 0x40 ? c - 0x30 : (c < 0x47 ? c - 0x37 : c - 0x57)) << 4);
            c = hexString[i * 2 + 1];
            b[i] += (byte)(c < 0x40 ? c - 0x30 : (c < 0x47 ? c - 0x37 : c - 0x57));
        }

        return b;
    }

Waleed Eissa功能，支持小写：

    public static string BytesToHex(this byte[] barray, bool toLowerCase = true)
    {
        byte addByte = 0x37;
        if (toLowerCase) addByte = 0x57;
        char[] c = new char[barray.Length * 2];
        byte b;
        for (int i = 0; i < barray.Length; ++i)
        {
            b = ((byte)(barray[i] >> 4));
            c[i * 2] = (char)(b > 9 ? b + addByte : b + 0x30);
            b = ((byte)(barray[i] & 0xF));
            c[i * 2 + 1] = (char)(b > 9 ? b + addByte : b + 0x30);
        }

        return new string(c);
    }

扩展方法（免责声明：完全未经测试的代码，BTW…）：

public static class ByteExtensions
{
    public static string ToHexString(this byte[] ba)
    {
        StringBuilder hex = new StringBuilder(ba.Length * 2);

        foreach (byte b in ba)
        {
            hex.AppendFormat("{0:x2}", b);
        }
        return hex.ToString();
    }
}

使用Tomalak的三种解决方案之一（最后一种是字符串上的扩展方法）。

两个mashup，将两个半字节操作合并为一个。

可能非常有效的版本：

public static string ByteArrayToString2(byte[] ba)
{
    char[] c = new char[ba.Length * 2];
    for( int i = 0; i < ba.Length * 2; ++i)
    {
        byte b = (byte)((ba[i>>1] >> 4*((i&1)^1)) & 0xF);
        c[i] = (char)(55 + b + (((b-10)>>31)&-7));
    }
    return new string( c );
}

Decadent linq与比特黑客版本：

public static string ByteArrayToString(byte[] ba)
{
    return string.Concat( ba.SelectMany( b => new int[] { b >> 4, b & 0xF }).Select( b => (char)(55 + b + (((b-10)>>31)&-7))) );
}

并反转：

public static byte[] HexStringToByteArray( string s )
{
    byte[] ab = new byte[s.Length>>1];
    for( int i = 0; i < s.Length; i++ )
    {
        int b = s[i];
        b = (b - '0') + ((('9' - b)>>31)&-7);
        ab[i>>1] |= (byte)(b << 4*((i&1)^1));
    }
    return ab;
}