这里不想赘述很多答案，但我发现了一个十六进制字符串解析器的相当优化（比公认的好4.5倍）、简单的实现。首先，我的测试输出（第一批是我的实现）：

Give me that string:
04c63f7842740c77e545bb0b2ade90b384f119f6ab57b680b7aa575a2f40939f

Time to parse 100,000 times: 50.4192 ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

Accepted answer: (StringToByteArray)
Time to parse 100000 times: 233.1264ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With Mono's implementation:
Time to parse 100000 times: 777.2544ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With SoapHexBinary:
Time to parse 100000 times: 845.1456ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

base64和“BitConverter'd”行用于测试正确性。请注意，它们是相等的。

实施：

public static byte[] ToByteArrayFromHex(string hexString)
{
  if (hexString.Length % 2 != 0) throw new ArgumentException("String must have an even length");
  var array = new byte[hexString.Length / 2];
  for (int i = 0; i < hexString.Length; i += 2)
  {
    array[i/2] = ByteFromTwoChars(hexString[i], hexString[i + 1]);
  }
  return array;
}

private static byte ByteFromTwoChars(char p, char p_2)
{
  byte ret;
  if (p <= '9' && p >= '0')
  {
    ret = (byte) ((p - '0') << 4);
  }
  else if (p <= 'f' && p >= 'a')
  {
    ret = (byte) ((p - 'a' + 10) << 4);
  }
  else if (p <= 'F' && p >= 'A')
  {
    ret = (byte) ((p - 'A' + 10) << 4);
  } else throw new ArgumentException("Char is not a hex digit: " + p,"p");

  if (p_2 <= '9' && p_2 >= '0')
  {
    ret |= (byte) ((p_2 - '0'));
  }
  else if (p_2 <= 'f' && p_2 >= 'a')
  {
    ret |= (byte) ((p_2 - 'a' + 10));
  }
  else if (p_2 <= 'F' && p_2 >= 'A')
  {
    ret |= (byte) ((p_2 - 'A' + 10));
  } else throw new ArgumentException("Char is not a hex digit: " + p_2, "p_2");

  return ret;
}

我尝试了一些不安全的东西，并将（显然是冗余的）字符移动到另一个方法来蚕食if序列，但这是最快的。

（我承认这回答了一半的问题。我觉得字符串->字节[]转换不足，而字节[]->字符串角度似乎被很好地覆盖了。因此，这个答案。）

我将参加这个比特拨弄比赛，因为我有一个同样使用比特拨弄来解码十六进制的答案。请注意，使用字符数组可能会更快，因为调用StringBuilder方法也需要时间。

public static String ToHex (byte[] data)
{
    int dataLength = data.Length;
    // pre-create the stringbuilder using the length of the data * 2, precisely enough
    StringBuilder sb = new StringBuilder (dataLength * 2);
    for (int i = 0; i < dataLength; i++) {
        int b = data [i];

        // check using calculation over bits to see if first tuple is a letter
        // isLetter is zero if it is a digit, 1 if it is a letter
        int isLetter = (b >> 7) & ((b >> 6) | (b >> 5)) & 1;

        // calculate the code using a multiplication to make up the difference between
        // a digit character and an alphanumerical character
        int code = '0' + ((b >> 4) & 0xF) + isLetter * ('A' - '9' - 1);
        // now append the result, after casting the code point to a character
        sb.Append ((Char)code);

        // do the same with the lower (less significant) tuple
        isLetter = (b >> 3) & ((b >> 2) | (b >> 1)) & 1;
        code = '0' + (b & 0xF) + isLetter * ('A' - '9' - 1);
        sb.Append ((Char)code);
    }
    return sb.ToString ();
}

public static byte[] FromHex (String hex)
{

    // pre-create the array
    int resultLength = hex.Length / 2;
    byte[] result = new byte[resultLength];
    // set validity = 0 (0 = valid, anything else is not valid)
    int validity = 0;
    int c, isLetter, value, validDigitStruct, validDigit, validLetterStruct, validLetter;
    for (int i = 0, hexOffset = 0; i < resultLength; i++, hexOffset += 2) {
        c = hex [hexOffset];

        // check using calculation over bits to see if first char is a letter
        // isLetter is zero if it is a digit, 1 if it is a letter (upper & lowercase)
        isLetter = (c >> 6) & 1;

        // calculate the tuple value using a multiplication to make up the difference between
        // a digit character and an alphanumerical character
        // minus 1 for the fact that the letters are not zero based
        value = ((c & 0xF) + isLetter * (-1 + 10)) << 4;

        // check validity of all the other bits
        validity |= c >> 7; // changed to >>, maybe not OK, use UInt?

        validDigitStruct = (c & 0x30) ^ 0x30;
        validDigit = ((c & 0x8) >> 3) * (c & 0x6);
        validity |= (isLetter ^ 1) * (validDigitStruct | validDigit);

        validLetterStruct = c & 0x18;
        validLetter = (((c - 1) & 0x4) >> 2) * ((c - 1) & 0x2);
        validity |= isLetter * (validLetterStruct | validLetter);

        // do the same with the lower (less significant) tuple
        c = hex [hexOffset + 1];
        isLetter = (c >> 6) & 1;
        value ^= (c & 0xF) + isLetter * (-1 + 10);
        result [i] = (byte)value;

        // check validity of all the other bits
        validity |= c >> 7; // changed to >>, maybe not OK, use UInt?

        validDigitStruct = (c & 0x30) ^ 0x30;
        validDigit = ((c & 0x8) >> 3) * (c & 0x6);
        validity |= (isLetter ^ 1) * (validDigitStruct | validDigit);

        validLetterStruct = c & 0x18;
        validLetter = (((c - 1) & 0x4) >> 2) * ((c - 1) & 0x2);
        validity |= isLetter * (validLetterStruct | validLetter);
    }

    if (validity != 0) {
        throw new ArgumentException ("Hexadecimal encoding incorrect for input " + hex);
    }

    return result;
}

从Java代码转换而来。

用@CodesInChaus补充答案（反向方法）

public static byte[] HexToByteUsingByteManipulation(string s)
{
    byte[] bytes = new byte[s.Length / 2];
    for (int i = 0; i < bytes.Length; i++)
    {
        int hi = s[i*2] - 65;
        hi = hi + 10 + ((hi >> 31) & 7);

        int lo = s[i*2 + 1] - 65;
        lo = lo + 10 + ((lo >> 31) & 7) & 0x0f;

        bytes[i] = (byte) (lo | hi << 4);
    }
    return bytes;
}

说明：

&0x0f还支持小写字母

hi=hi+10+（（hi>>31）&7）；与以下内容相同：

hi=ch-65+10+（（ch-65）>>31）&7）；

对于“0”9’与hi＝ch-65+10+7相同；其为hi＝ch-48（这是因为0xffffff&7）。

对于“A”F’为hi=ch-65+10；（这是因为0x00000000&7）。

对于“a”我们必须使用大数字，所以我们必须通过使用&0x0f使某些位为0，从默认版本中减去32。

65是“A”的代码

48是“0”的代码

7是ASCII表中“9”和“A”之间的字母数（…456789:；<=>？@ABCD…）。

为了方便以后复制和粘贴，将几个答案合并到一个类中：

/// <summary>
/// Extension methods to quickly convert byte array to string and back.
/// </summary>
public static class HexConverter
{
    /// <summary>
    /// Map values to hex digits
    /// </summary>
    private static readonly char[] HexDigits =
        {
            '0', '1', '2', '3', '4', '5', '6', '7', '8', '9', 'A', 'B', 'C', 'D', 'E', 'F'
        };

    /// <summary>
    /// Map 56 characters between ['0', 'F'] to their hex equivalents, and set invalid characters
    /// such that they will overflow byte to fail conversion.
    /// </summary>
    private static readonly ushort[] HexValues =
        {
            0x0000, 0x0001, 0x0002, 0x0003, 0x0004, 0x0005, 0x0006, 0x0007, 0x0008, 0x0009, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100,
            0x000A, 0x000B, 0x000C, 0x000D, 0x000E, 0x000F, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100,
            0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x000A, 0x000B,
            0x000C, 0x000D, 0x000E, 0x000F
        };

    /// <summary>
    /// Empty byte array 
    /// </summary>
    private static readonly byte[] Empty = new byte[0];

    /// <summary>
    /// Convert a byte array to a hexadecimal string.
    /// </summary>
    /// <param name="bytes">
    /// The input byte array.
    /// </param>
    /// <returns>
    /// A string of hexadecimal digits.
    /// </returns>
    public static string ToHexString(this byte[] bytes)
    {
        var c = new char[bytes.Length * 2];
        for (int i = 0, j = 0; i < bytes.Length; i++)
        {
            c[j++] = HexDigits[bytes[i] >> 4];
            c[j++] = HexDigits[bytes[i] & 0x0F];
        }

        return new string(c);
    }

    /// <summary>
    /// Parse a string of hexadecimal digits into a byte array.
    /// </summary>
    /// <param name="hexadecimalString">
    /// The hexadecimal string.
    /// </param>
    /// <returns>
    /// The parsed <see cref="byte[]"/> array.
    /// </returns>
    /// <exception cref="ArgumentException">
    /// The input string either contained invalid characters, or was of an odd length.
    /// </exception>
    public static byte[] ToByteArray(string hexadecimalString)
    {
        if (!TryParse(hexadecimalString, out var value))
        {
            throw new ArgumentException("Invalid hexadecimal string", nameof(hexadecimalString));
        }

        return value;
    }

    /// <summary>
    /// Parse a hexadecimal string to bytes
    /// </summary>
    /// <param name="hexadecimalString">
    /// The hexadecimal string, which must be an even number of characters.
    /// </param>
    /// <param name="value">
    /// The parsed value if successful.
    /// </param>
    /// <returns>
    /// True if successful.
    /// </returns>
    public static bool TryParse(string hexadecimalString, out byte[] value)
    {
        if (hexadecimalString.Length == 0)
        {
            value = Empty;
            return true;
        }

        if (hexadecimalString.Length % 2 != 0)
        {
            value = Empty;
            return false;
        }

        try
        {

            value = new byte[hexadecimalString.Length / 2];
            for (int i = 0, j = 0; j < hexadecimalString.Length; i++)
            {
                value[i] = (byte)((HexValues[hexadecimalString[j++] - '0'] << 4)
                                  | HexValues[hexadecimalString[j++] - '0']);
            }

            return true;
        }
        catch (OverflowException)
        {
            value = Empty;
            return false;
        }
    }
}

我今天遇到了同样的问题，我遇到了以下代码：

private static string ByteArrayToHex(byte[] barray)
{
    char[] c = new char[barray.Length * 2];
    byte b;
    for (int i = 0; i < barray.Length; ++i)
    {
        b = ((byte)(barray[i] >> 4));
        c[i * 2] = (char)(b > 9 ? b + 0x37 : b + 0x30);
        b = ((byte)(barray[i] & 0xF));
        c[i * 2 + 1] = (char)(b > 9 ? b + 0x37 : b + 0x30);
    }
    return new string(c);
}

来源：论坛帖子byte[]数组到十六进制字符串（见PZahra的帖子）。我稍微修改了一下代码，删除了0x前缀。

我对代码进行了一些性能测试，它几乎比使用BitConverter.ToString（）快八倍（根据patridge的帖子，速度最快）。

    // a safe version of the lookup solution:       

    public static string ByteArrayToHexViaLookup32Safe(byte[] bytes, bool withZeroX)
    {
        if (bytes.Length == 0)
        {
            return withZeroX ? "0x" : "";
        }

        int length = bytes.Length * 2 + (withZeroX ? 2 : 0);
        StateSmall stateToPass = new StateSmall(bytes, withZeroX);
        return string.Create(length, stateToPass, (chars, state) =>
        {
            int offset0x = 0;
            if (state.WithZeroX)
            {
                chars[0] = '0';
                chars[1] = 'x';
                offset0x += 2;
            }

            Span<uint> charsAsInts = MemoryMarshal.Cast<char, uint>(chars.Slice(offset0x));
            int targetLength = state.Bytes.Length;
            for (int i = 0; i < targetLength; i += 1)
            {
                uint val = Lookup32[state.Bytes[i]];
                charsAsInts[i] = val;
            }
        });
    }

    private struct StateSmall
    {
        public StateSmall(byte[] bytes, bool withZeroX)
        {
            Bytes = bytes;
            WithZeroX = withZeroX;
        }

        public byte[] Bytes;
        public bool WithZeroX;
    }