没有测试性能，但在linq的一行中:

var val = "ThisIsAStringToTest";
val = string.Concat(val.Select(x => Char.IsUpper(x) ? " " + x : x.ToString())).TrimStart(' ');

这个正则表达式在每个大写字母前放置一个空格字符:

using System.Text.RegularExpressions;

const string myStringWithoutSpaces = "ThisIsAStringWithoutSpaces";
var myStringWithSpaces = Regex.Replace(myStringWithoutSpaces, "([A-Z])([a-z]*)", " $1$2");

注意前面的空间，如果“$1$2”，这是可以完成的。

结果如下:

"This Is A String Without Spaces"

受到二元忧虑者答案的启发，我尝试了一下。

结果如下:

/// <summary>
/// String Extension Method
/// Adds white space to strings based on Upper Case Letters
/// </summary>
/// <example>
/// strIn => "HateJPMorgan"
/// preserveAcronyms false => "Hate JP Morgan"
/// preserveAcronyms true => "Hate JPMorgan"
/// </example>
/// <param name="strIn">to evaluate</param>
/// <param name="preserveAcronyms" >determines saving acronyms (Optional => false) </param>
public static string AddSpaces(this string strIn, bool preserveAcronyms = false)
{
    if (string.IsNullOrWhiteSpace(strIn))
        return String.Empty;

    var stringBuilder = new StringBuilder(strIn.Length * 2)
        .Append(strIn[0]);

    int i;

    for (i = 1; i < strIn.Length - 1; i++)
    {
        var c = strIn[i];

        if (Char.IsUpper(c) && (Char.IsLower(strIn[i - 1]) || (preserveAcronyms && Char.IsLower(strIn[i + 1]))))
            stringBuilder.Append(' ');

        stringBuilder.Append(c);
    }

    return stringBuilder.Append(strIn[i]).ToString();
}

测试使用秒表运行10000000次迭代和各种字符串长度和组合。

平均比二进制忧虑者的答案快50%(可能多一点)。

仅由ASCII字符组成的输入字符串的c#解决方案。regex结合了反向回溯来忽略出现在字符串开头的大写字母。使用Regex.Replace()返回所需的字符串。

参见regex101.com演示。

using System;
using System.Text.RegularExpressions;

public class RegexExample
{
    public static void Main()
    {
        var text = "ThisStringHasNoSpacesButItDoesHaveCapitals";

        // Use negative lookbehind to match all capital letters
        // that do not appear at the beginning of the string.
        var pattern = "(?<!^)([A-Z])";

        var rgx = new Regex(pattern);
        var result = rgx.Replace(text, " $1");
        Console.WriteLine("Input: [{0}]\nOutput: [{1}]", text, result);
    }
}

预期的输出:

Input: [ThisStringHasNoSpacesButItDoesHaveCapitals]
Output: [This String Has No Spaces But It Does Have Capitals]

更新:这里有一个变种，也将处理首字母缩写(大写字母序列)。

参见regex101.com演示和ideone.com演示。

using System;
using System.Text.RegularExpressions;

public class RegexExample
{
    public static void Main()
    {
        var text = "ThisStringHasNoSpacesASCIIButItDoesHaveCapitalsLINQ";

        // Use positive lookbehind to locate all upper-case letters
        // that are preceded by a lower-case letter.
        var patternPart1 = "(?<=[a-z])([A-Z])";

        // Used positive lookbehind and lookahead to locate all
        // upper-case letters that are preceded by an upper-case
        // letter and followed by a lower-case letter.
        var patternPart2 = "(?<=[A-Z])([A-Z])(?=[a-z])";

        var pattern = patternPart1 + "|" + patternPart2;
        var rgx = new Regex(pattern);
        var result = rgx.Replace(text, " $1$2");

        Console.WriteLine("Input: [{0}]\nOutput: [{1}]", text, result);
    }
}

预期的输出:

Input: [ThisStringHasNoSpacesASCIIButItDoesHaveCapitalsLINQ]
Output: [This String Has No Spaces ASCII But It Does Have Capitals LINQ]

    private string GetProperName(string Header)
    {
        if (Header.ToCharArray().Where(c => Char.IsUpper(c)).Count() == 1)
        {
            return Header;
        }
        else
        {
            string ReturnHeader = Header[0].ToString();
            for(int i=1; i<Header.Length;i++)
            {
                if (char.IsLower(Header[i-1]) && char.IsUpper(Header[i]))
                {
                    ReturnHeader += " " + Header[i].ToString();
                }
                else
                {
                    ReturnHeader += Header[i].ToString();
                }
            }

            return ReturnHeader;
        }

        return Header;
    }

这对聚合来说是个好机会。它被设计成可读的，但不一定特别快。

someString
.Aggregate(
   new StringBuilder(),
   (str, ch) => {
      if (char.IsUpper(ch) && str.Length > 0)
         str.Append(" ");
      str.Append(ch);
      return str;
   }
).ToString();