var now = System.DateTime.Now;

var result = now.AddDays(-((now.DayOfWeek - System.Threading.Thread.CurrentThread.CurrentCulture.DateTimeFormat.FirstDayOfWeek + 7) % 7)).Date;

下面的方法应该返回所需的DateTime。周日为true，周一为false:

private DateTime getStartOfWeek(bool useSunday)
{
    DateTime now = DateTime.Now;
    int dayOfWeek = (int)now.DayOfWeek;

    if(!useSunday)
        dayOfWeek--;

    if(dayOfWeek < 0)
    {// day of week is Sunday and we want to use Monday as the start of the week
    // Sunday is now the seventh day of the week
        dayOfWeek = 6;
    }

    return now.AddDays(-1 * (double)dayOfWeek);
}

var now = System.DateTime.Now;

var result = now.AddDays(-((now.DayOfWeek - System.Threading.Thread.CurrentThread.CurrentCulture.DateTimeFormat.FirstDayOfWeek + 7) % 7)).Date;

周末也一样(以Compile This's answer的方式):

    public static DateTime EndOfWeek(this DateTime dt)
    {
        int diff = 7 - (int)dt.DayOfWeek;

        diff = diff == 7 ? 0 : diff;

        DateTime eow = dt.AddDays(diff).Date;

        return new DateTime(eow.Year, eow.Month, eow.Day, 23, 59, 59, 999) { };
    }

以下是一些答案的组合。它使用一个扩展方法，允许传入区域性。如果没有传入，则使用当前区域性。这将为它提供最大的灵活性和重用性。

/// <summary>
/// Gets the date of the first day of the week for the date.
/// </summary>
/// <param name="date">The date to be used</param>
/// <param name="cultureInfo">If none is provided, the current culture is used</param>
/// <returns>The date of the beggining of the week based on the culture specifed</returns>
public static DateTime StartOfWeek(this DateTime date, CultureInfo cultureInfo=null) =>
    date.AddDays(-1 * (7 + (date.DayOfWeek - (cultureInfo ?? CultureInfo.CurrentCulture).DateTimeFormat.FirstDayOfWeek)) % 7).Date;

使用示例:

public static void TestFirstDayOfWeekExtension() {
    DateTime date = DateTime.Now;
    foreach(System.Globalization.CultureInfo culture in CultureInfo.GetCultures(CultureTypes.UserCustomCulture | CultureTypes.SpecificCultures)) {
        Console.WriteLine($"{culture.EnglishName}: {date.ToShortDateString()} First Day of week: {date.StartOfWeek(culture).ToShortDateString()}");
    }
}

周一

DateTime startAtMonday = DateTime.Now.AddDays(DayOfWeek.Monday - DateTime.Now.DayOfWeek);

在周日

DateTime startAtSunday = DateTime.Now.AddDays(DayOfWeek.Sunday- DateTime.Now.DayOfWeek);