Material Components 1.4.0-alpha02中的MaterialToolbar现在能够通过设置titleCentered属性为true来居中工具栏的标题:

<com.google.android.material.appbar.AppBarLayout
    android:id="@+id/appBarLayout"
    android:layout_width="match_parent"
    android:layout_height="wrap_content">

    <com.google.android.material.appbar.MaterialToolbar
        android:id="@+id/topAppBar"
        style="@style/Widget.MaterialComponents.Toolbar.Primary"
        android:layout_width="match_parent"
        android:layout_height="?attr/actionBarSize"
        app:titleCentered="true" />

</com.google.android.material.appbar.AppBarLayout>

    public class TestActivity extends AppCompatActivity {
    private Toolbar toolbar;

    @Override
    protected void onCreate(Bundle savedInstanceState) {
        super.onCreate(savedInstanceState);
        super.setContentView(R.layout.activity_test);

        toolbar = (Toolbar) findViewById(R.id.tool_bar); // Attaching the layout to the toolbar object
        setSupportActionBar(toolbar);

        customizeToolbar(toolbar);
    }

    public void customizeToolbar(Toolbar toolbar){
        // Save current title and subtitle
        final CharSequence originalTitle = toolbar.getTitle();
        final CharSequence originalSubtitle = toolbar.getSubtitle();

        // Temporarily modify title and subtitle to help detecting each
        toolbar.setTitle("title");
        toolbar.setSubtitle("subtitle");

        for(int i = 0; i < toolbar.getChildCount(); i++){
            View view = toolbar.getChildAt(i);

            if(view instanceof TextView){
                TextView textView = (TextView) view;


                if(textView.getText().equals("title")){
                    // Customize title's TextView
                    Toolbar.LayoutParams params = new Toolbar.LayoutParams(Toolbar.LayoutParams.WRAP_CONTENT, Toolbar.LayoutParams.MATCH_PARENT);
                    params.gravity = Gravity.CENTER_HORIZONTAL;
                    textView.setLayoutParams(params);

                    // Apply custom font using the Calligraphy library
                    Typeface typeface = TypefaceUtils.load(getAssets(), "fonts/myfont-1.otf");
                    textView.setTypeface(typeface);

                } else if(textView.getText().equals("subtitle")){
                    // Customize subtitle's TextView
                    Toolbar.LayoutParams params = new Toolbar.LayoutParams(Toolbar.LayoutParams.WRAP_CONTENT, Toolbar.LayoutParams.MATCH_PARENT);
                    params.gravity = Gravity.CENTER_HORIZONTAL;
                    textView.setLayoutParams(params);

                    // Apply custom font using the Calligraphy library
                    Typeface typeface = TypefaceUtils.load(getAssets(), "fonts/myfont-2.otf");
                    textView.setTypeface(typeface);
                }
            }
        }

        // Restore title and subtitle
        toolbar.setTitle(originalTitle);
        toolbar.setSubtitle(originalSubtitle);
    }
}

更新自@MrEngineer13的回答:要在任何情况下对齐标题中心，包括汉堡图标，选项菜单，你可以在工具栏中添加一个框架布局，像这样:

   <android.support.v7.widget.Toolbar
    android:id="@+id/toolbar_top"
    android:layout_height="wrap_content"
    android:layout_width="match_parent"
    android:minHeight="?attr/actionBarSize"
    android:background="@color/action_bar_bkgnd"
    app:theme="@style/ToolBarTheme" >

         <FrameLayout android:layout_width="match_parent"
                    android:layout_height="match_parent">

              <TextView
               android:layout_width="wrap_content"
               android:layout_height="wrap_content"
               android:text="Toolbar Title"
               android:layout_gravity="center"
               style="@style/TextAppearance.AppCompat.Widget.ActionBar.Title"
               android:id="@+id/toolbar_title" />

        </FrameLayout>

   </android.support.v7.widget.Toolbar>

我使用这个解决方案:

static void centerToolbarTitle(@NonNull final Toolbar toolbar) {
    final CharSequence title = toolbar.getTitle();
    final ArrayList<View> outViews = new ArrayList<>(1);
    toolbar.findViewsWithText(outViews, title, View.FIND_VIEWS_WITH_TEXT);
    if (!outViews.isEmpty()) {
        final TextView titleView = (TextView) outViews.get(0);
        titleView.setGravity(Gravity.CENTER);
        final Toolbar.LayoutParams layoutParams = (Toolbar.LayoutParams) titleView.getLayoutParams();
        layoutParams.width = ViewGroup.LayoutParams.MATCH_PARENT;
        toolbar.requestLayout();
        //also you can use titleView for changing font: titleView.setTypeface(Typeface);
    }
}

没有工具栏TextView，我们可以自定义字体使用下面的代码

getSupportActionBar().setDisplayShowTitleEnabled(false);
or
getActionBar().setDisplayShowTitleEnabled(false);

public void updateActionbar(String title){
    SpannableString spannableString = new SpannableString(title);
    spannableString.setSpan(new TypefaceSpanString(this,  "futurastdmedium.ttf"),
            0, spannableString.length(),
            Spannable.SPAN_EXCLUSIVE_EXCLUSIVE);
    mToolbar.setTitle(spannableString);
}

private void makeTitleCenter(String title, Toolbar toolbar) {
    if (title != null && !TextUtils.isEmpty(title.trim())) {
        final String tag = " ";
        if (getSupportActionBar() != null) {
            getSupportActionBar().setTitle(tag);
        }
        TextView titleTv = null;
        View leftBtn = null;
        for (int i = 0; i < toolbar.getChildCount(); i++) {
            View view = toolbar.getChildAt(i);
            CharSequence text = null;
            if (view instanceof TextView && (text = ((TextView) view).getText()) != null && text.equals(tag)) {
                titleTv = (TextView) view;
            } else if (view instanceof ImageButton) {
                leftBtn = view;
            }
        }
        if (titleTv != null) {
            final TextView fTitleTv = titleTv;
            final View fLeftBtn = leftBtn;
            fTitleTv.getViewTreeObserver().addOnGlobalLayoutListener(new ViewTreeObserver.OnGlobalLayoutListener() {
                @Override
                public void onGlobalLayout() {
                    fTitleTv.getViewTreeObserver().removeOnGlobalLayoutListener(this);
                    int leftWidgetWidth = fLeftBtn != null ? fLeftBtn.getWidth() : 0;
                    fTitleTv.setPadding(DimenUtil.getResources().getDisplayMetrics().widthPixels / 2 - leftWidgetWidth - fTitleTv.getWidth() / 2, 0, 0, 0);
                    fTitleTv.requestLayout();
                }
            });
        }
    }
}