这也可以用这种方式来完成

        string actualString = "1111222233334444";
        var listResult = new List<string>();
        int groupingLength = actualString.Length % 4;
        if (groupingLength > 0)
            listResult.Add(actualString.Substring(0, groupingLength));
        for (int i = groupingLength; i < actualString.Length; i += 4)
        {
            listResult.Add(actualString.Substring(i, 4));
        }

        foreach(var res in listResult)
        {
            Console.WriteLine(res);
        }
        Console.Read();

最近我不得不在工作中写一些东西来完成这个任务，所以我想我会把我对这个问题的解决方案贴出来。作为一个额外的好处，这个解决方案的功能提供了一种方法，以相反的方向分割字符串，并且它正确地处理上面Marvin Pinto提到的unicode字符。所以，就是这样:

using System;
using Extensions;

namespace TestCSharp
{
    class Program
    {
        static void Main(string[] args)
        {    
            string asciiStr = "This is a string.";
            string unicodeStr = "これは文字列です。";

            string[] array1 = asciiStr.Split(4);
            string[] array2 = asciiStr.Split(-4);

            string[] array3 = asciiStr.Split(7);
            string[] array4 = asciiStr.Split(-7);

            string[] array5 = unicodeStr.Split(5);
            string[] array6 = unicodeStr.Split(-5);
        }
    }
}

namespace Extensions
{
    public static class StringExtensions
    {
        /// <summary>Returns a string array that contains the substrings in this string that are seperated a given fixed length.</summary>
        /// <param name="s">This string object.</param>
        /// <param name="length">Size of each substring.
        ///     <para>CASE: length &gt; 0 , RESULT: String is split from left to right.</para>
        ///     <para>CASE: length == 0 , RESULT: String is returned as the only entry in the array.</para>
        ///     <para>CASE: length &lt; 0 , RESULT: String is split from right to left.</para>
        /// </param>
        /// <returns>String array that has been split into substrings of equal length.</returns>
        /// <example>
        ///     <code>
        ///         string s = "1234567890";
        ///         string[] a = s.Split(4); // a == { "1234", "5678", "90" }
        ///     </code>
        /// </example>            
        public static string[] Split(this string s, int length)
        {
            System.Globalization.StringInfo str = new System.Globalization.StringInfo(s);

            int lengthAbs = Math.Abs(length);

            if (str == null || str.LengthInTextElements == 0 || lengthAbs == 0 || str.LengthInTextElements <= lengthAbs)
                return new string[] { str.ToString() };

            string[] array = new string[(str.LengthInTextElements % lengthAbs == 0 ? str.LengthInTextElements / lengthAbs: (str.LengthInTextElements / lengthAbs) + 1)];

            if (length > 0)
                for (int iStr = 0, iArray = 0; iStr < str.LengthInTextElements && iArray < array.Length; iStr += lengthAbs, iArray++)
                    array[iArray] = str.SubstringByTextElements(iStr, (str.LengthInTextElements - iStr < lengthAbs ? str.LengthInTextElements - iStr : lengthAbs));
            else // if (length < 0)
                for (int iStr = str.LengthInTextElements - 1, iArray = array.Length - 1; iStr >= 0 && iArray >= 0; iStr -= lengthAbs, iArray--)
                    array[iArray] = str.SubstringByTextElements((iStr - lengthAbs < 0 ? 0 : iStr - lengthAbs + 1), (iStr - lengthAbs < 0 ? iStr + 1 : lengthAbs));

            return array;
        }
    }
}

此外，这里还有一个运行此代码结果的图像链接:http://i.imgur.com/16Iih.png

六年后o_O

仅仅因为

    public static IEnumerable<string> Split(this string str, int chunkSize, bool remainingInFront)
    {
        var count = (int) Math.Ceiling(str.Length/(double) chunkSize);
        Func<int, int> start = index => remainingInFront ? str.Length - (count - index)*chunkSize : index*chunkSize;
        Func<int, int> end = index => Math.Min(str.Length - Math.Max(start(index), 0), Math.Min(start(index) + chunkSize - Math.Max(start(index), 0), chunkSize));
        return Enumerable.Range(0, count).Select(i => str.Substring(Math.Max(start(i), 0),end(i)));
    }

or

    private static Func<bool, int, int, int, int, int> start = (remainingInFront, length, count, index, size) =>
        remainingInFront ? length - (count - index) * size : index * size;

    private static Func<bool, int, int, int, int, int, int> end = (remainingInFront, length, count, index, size, start) =>
        Math.Min(length - Math.Max(start, 0), Math.Min(start + size - Math.Max(start, 0), size));

    public static IEnumerable<string> Split(this string str, int chunkSize, bool remainingInFront)
    {
        var count = (int)Math.Ceiling(str.Length / (double)chunkSize);
        return Enumerable.Range(0, count).Select(i => str.Substring(
            Math.Max(start(remainingInFront, str.Length, count, i, chunkSize), 0),
            end(remainingInFront, str.Length, count, i, chunkSize, start(remainingInFront, str.Length, count, i, chunkSize))
        ));
    }

AFAIK所有的边缘情况都处理好了。

Console.WriteLine(string.Join(" ", "abc".Split(2, false))); // ab c
Console.WriteLine(string.Join(" ", "abc".Split(2, true))); // a bc
Console.WriteLine(string.Join(" ", "a".Split(2, true))); // a
Console.WriteLine(string.Join(" ", "a".Split(2, false))); // a

从。net 6开始，我们还可以使用Chunk方法:

var result = str
    .Chunk(4)
    .Select(x => new string(x))
    .ToList();

public static IEnumerable<IEnumerable<T>> SplitEvery<T>(this IEnumerable<T> values, int n)
{
    var ls = values.Take(n);
    var rs = values.Skip(n);
    return ls.Any() ?
        Cons(ls, SplitEvery(rs, n)) : 
        Enumerable.Empty<IEnumerable<T>>();
}

public static IEnumerable<T> Cons<T>(T x, IEnumerable<T> xs)
{
    yield return x;
    foreach (var xi in xs)
        yield return xi;
}

最好，最简单和一般的答案:)。

    string originalString = "1111222233334444";
    List<string> test = new List<string>();
    int chunkSize = 4; // change 4 with the size of strings you want.
    for (int i = 0; i < originalString.Length; i = i + chunkSize)
    {
        if (originalString.Length - i >= chunkSize)
            test.Add(originalString.Substring(i, chunkSize));
        else
            test.Add(originalString.Substring(i,((originalString.Length - i))));
    }